|
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[glycerolipid]-di-homo-gamma-linolenate + ferricytochrome_b5 + O2 + H+ <=> [glycerolipid]-arachidonate + ferricytochrome_b5 + H2O
|
1.14.19.30
acyl-lipid (8-3)-desaturase
|
–
|
|
MetaCyc:
RXN-8346
|
|
|
|
(11Z,14Z)-icosa-11,14-dienoyl-CoA + NADP+ <=> (2E,11Z,14Z)-icosatrienoyl-CoA + NADPH + H+
|
1.3.1.93
very-long-chain enoyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-16097
|
|
|
|
(3R,11Z,14Z)-3-hydroxyicosadienoyl-CoA <=> (2E,11Z,14Z)-icosatrienoyl-CoA + H2O
|
4.2.1.134
very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase
|
–
|
|
MetaCyc:
RXN-16096
|
|
|
|
[glycerolipid]-(11Z,14Z)-icosadienoate + O2 + ferricytochrome_b5 + H+ <=> [glycerolipid]-di-homo-gamma-linolenate + H2O + ferricytochrome_b5
|
1.14.19.4
acyl-lipid (11-3)-desaturase
|
–
|
|
MetaCyc:
RXN-16099
|
|
|
|
(3R,11Z,14Z)-3-hydroxyicosadienoyl-CoA + NADP+ <=> (11Z,14Z)-3-oxoicosadienoyl-CoA + NADPH + H+
|
1.1.1.330
very-long-chain 3-oxoacyl-CoA reductase
|
–
|
|
MetaCyc:
RXN-16095
|
|
|
|
malonyl-CoA + linoleoyl-CoA + H+ <=> (11Z,14Z)-3-oxoicosadienoyl-CoA + CO2 + CoA
|
2.3.1.199
very-long-chain 3-oxoacyl-CoA synthase
|
–
|
|
MetaCyc:
RXN-16094
|
|
|
|
(11Z,14Z)-icosa-11,14-dienoyl-CoA + glycerolipid <=> [glycerolipid]-(11Z,14Z)-icosadienoate + CoA
|
2.3.1
|
–
|
|
MetaCyc:
RXN-16098
|
|